Journal
CHINESE JOURNAL OF CATALYSIS
Volume 34, Issue 11, Pages 2084-2088Publisher
SCIENCE PRESS
DOI: 10.1016/S1872-2067(12)60665-2
Keywords
Nanocatalyst; Palladium; Transfer hydrogenation; In-situ synthesis; Azo
Funding
- National Natural Science Foundation of China [21003092]
- Key Project of Chinese Ministry of Education [211064]
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We developed a simple and efficient method to synthesize aromatic azos by hydrogen transfer using palladium(II) acetylacetonate as a catalyst and isopropyl alcohol as a hydrogen source. Furthermore, this system also showed catalytic potential for the hydrogenation of carbonyl groups or C=C bonds with yields up to similar to 97%. (C) 2013, Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. All rights reserved.
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