Journal
MATERIALS RESEARCH BULLETIN
Volume 98, Issue -, Pages 187-193Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.materresbull.2017.10.025
Keywords
Upconversion; Phosphor; Ba3Sc4O9; Energy transfer
Categories
Funding
- Natural Science Foundation of China [51304086, 11464017]
- Foundation of Science and Technology Pillar Program in Industrial Field of Jiangxi Province [20123BBE50075]
- Natural Science Funds for Distinguished Young Scholar of Jiangxi Province [20171BCB23064]
- Science & Technology Major Project of Jiangxi Province [20165ABC28010]
- Program of Qingjiang Excellent Young Talents of Jiangxi University of Science and Technology
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A series of Ba3Sc4O5:Ho3+/Yb3+ phosphors were synthesized by a high-temperature solid-state reaction method. The phase purity and upconversion luminescence were characterized by X-ray diffraction and photoluminescence spectroscopy. The sintering temperature and doping concentrations were optimized to obtain the strongest emission intensity. Under 980 nm laser diode excitation, the green (545 nm, F-5(4)/S-5(2) -> I-5(8)) and red (665 nm, F-5(5) -> I-5(8)) emissions were observed. The cross-relaxation and back-energy-transfer processes play an important role to adjust the emission intensity ratio of Green/Red at different dopant concentrations. Based on the energy level diagrams, the energy transfer mechanisms are investigated in detail according to the analysis of pump power dependence and luminescence decay curves. The upconversion luminescence properties of the phosphor were evaluated and the results show good color monochromaticity and relatively high upconversion luminescence intensity. The Ba3Sc4O5:Ho3+/Yb3+ can be a good candidate for green upconversion material in display fields and fluorescent labeling.
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