4.6 Article

Energy transfer and tunable emission of Ca14Al10Zn6O35:Bi3+,Sm3+ phosphor

Journal

MATERIALS RESEARCH BULLETIN
Volume 100, Issue -, Pages 56-61

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.materresbull.2017.12.003

Keywords

Ca14Al10Zn6O35; Phosphors; Energy transfer; Bi3+Sm3+

Funding

  1. National Natural Science Foundation of China [21371062, 21671070, 21571067]
  2. Project for Construction of High-level University in Guangdong Province
  3. Guangdong Natural Science Foundation [S2013030012842]
  4. Provincial Science and technology project of Guangdong Province [2016A050502043]
  5. Guangzhou Science & Technology Project [201704030086, 201605030005]
  6. Spectral Funds for the Cultivation of Guangdong College Student Scientific and Technological Innovation (Climbing Program Special Funds) [pdjh2017a0075]

Ask authors/readers for more resources

A series of Bi3+ Sm3+-codoped Ca14Al10Zn6O35 phosphors were synthesized via conventional high temperature solid-state method. The crystal structure, morphology, photoluminescence and energy transfer mechanism from Bi3+ to Sm3+ were investigated in detail. A broad blue emission band due to P-3(1) -> S-1(0) transition of Be3+ was observed in the Bi3+ single-doped Ca14Al10Zn6O35 sample, the Ca2+ position are verified to be replaced by Bi3+ and the corresponding concentration quenching mechanism was dipole-dipole interaction. The considerable spectral overlap between the broad emission band of Bi3+ around 350-550 nm and the excitation band of Sm3+ supports the energy transfer from Bi3+ to Sm3+. This investigation will contribute to the comprehension of interactions between Bi3+ and Sm3+. These results reveal the potential application of Bi3+, Sm3+ co-doped phosphor in UV light-emitting diodes and artificial light in plant.

Authors

I am an author on this paper
Click your name to claim this paper and add it to your profile.

Reviews

Primary Rating

4.6
Not enough ratings

Secondary Ratings

Novelty
-
Significance
-
Scientific rigor
-
Rate this paper

Recommended

No Data Available
No Data Available