4.7 Article

Dual-Functional Conjugated Nanoporous Polymers for Efficient Organic Pollutants Treatment in Water: A Synergistic Strategy of Adsorption and Photocatalysis

Journal

MACROMOLECULES
Volume 51, Issue 9, Pages 3443-3449

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/acs.macromol.8b00669

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Funding

  1. National Natural Science Foundation of China [51522303, 21602154]
  2. National Key Research and Development Program of China [2017YFA0207500]

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A series of 9,9'-bifluorenylidene-based conjugated microporous/mesoporous polymers (BF-CMPs) were constructed via Suzuki polycondensation. The porosities and electronic properties of BF-CMPs can be readily tuned by selection of proper monomers. Among three BF-CMPs, Py-BF-CMP exhibited an extraordinarily high adsorption capacity (1905 mg g(-1)) and excellent photocatalytic degradation performance of organic dyes in water. Moreover, Py-BF-CMP featured good recyclabiity with both high adsorption degree (99%) and photodegradation efficiency (92%) of RhB even after 10 recycles.

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