Timing and duration of Variscan high-pressure metamorphism in the French Massif Central: A multimethod geochronological study from the Najac Massif

Accurate dating of eclogite-facies metamorphism is of paramount importance in order to understand the tectonic evolution of an orogen. An eclogite sample from the Najac Massif (French Massif Central, Variscan belt) displays a zircon-bearing garnet-omphacite-amphibole-rutile-quartz peak assemblage. Pseudosection modeling suggests peak pressure conditions of 15-20 kbar, 560-630 degrees C. Eclogite-facies garnet displays Lu-enriched cores and Sm-rich rims and yields a Lu-Hf age of 382.8 +/- 1.0 Ma and a Sm-Nd age of 376.7 +/- 3.3 Ma. The ages are interpreted as marking the beginning of the prograde garnet growth during the initial stages of the eclogite-facies metamorphism, and the high-pressure (and temperature) peak reached by the rock, respectively. Zircon grains display chondrite-normalized REE spectra with variably negative, positive or no Eu anomalies and are characterized by either enriched or flat HREE patterns. However, they yield a well constrained in situ LA-ICP-MS U-Pb age of 385.5 +/- 2.3 Ma, despite this REE pattern variability. Zr zonation in garnet, Y content in zircon and the diversity of zircon HREE spectra may suggest that zircon crystallized prior to and during incipient garnet growth on the prograde P-T path, recording the initial stages of the eclogite-facies conditions. Consequently, the zircon age of 385.5 +/- 23 Ma, comparable within error with the Lu-Hf age obtained on garnet, is interpreted as dating the beginning of the eclogite-facies metamorphism. Accordingly, the duration of the prograde part of the eclogite-facies event is estimated at 6.1 +/- 4.3 Myr. Subsequent exhumation is constrained by an apatite U-Pb age at 369 +/- 13 Ma. (C) 2018 Elsevier B.V. All rights reserved.