Journal
JOURNAL OF THE EUROPEAN CERAMIC SOCIETY
Volume 38, Issue 14, Pages 4707-4718Publisher
ELSEVIER SCI LTD
DOI: 10.1016/j.jeurceramsoc.2018.06.014
Keywords
Lithium garnet; Air exposure; Phase (in)stability; Structural (in)stability; Mechanical (in)stability
Categories
Funding
- IRCC (IIT Bombay, India) [RI/0215-10001195-001]
Ask authors/readers for more resources
Among the Li-ion conducting inorganic materials, lithium lanthanum zirconate (LLZO) is believed to possess good chemical stability against Li metal and hence considered to be a promising solid electrolyte for Li-ion batteries. However, systematic sets of studies conducted here at regular intervals during storage of Al-doped LLZO (cubic garnet) sintered pellets in ambient atmosphere have raised serious concerns over their structural/ mechanical stability/integrity upon exposure to air. Spontaneous cracking/disintegration/pulverization of LLZO pellets takes place after about three weeks of exposure, primarily due to formation of La2Zr2O2 in the LLZO bulk; as found to be thermodynamically feasible at room temperature upon reaction with CO2/moisture. Steep increase in ZrLa2Zr2O2 content coincides with the spontaneous cracking/disintegration. Estimation suggests that internal stresses associated with the formation of La2Zr2O2 from LLZO can be high enough to cause spontaneous fracture. This mandates the development/fabrication/usage of solid-state cells using LLZO under stringent controls against exposure to atmospheric species.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available