Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 140, Issue 30, Pages 9400-9403Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jacs.8b05743
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Funding
- NSFC [21622206, 21472179]
- MOST of China [2015CB856600]
- Chinese Academy of Sciences [XDB20000000]
- Fundamental Research Funds for the Central Universities [WK2060190086]
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A Cu-catalyzed enantioselective desymmetrizing ring-opening reaction of six-membered cyclic diaryliodonium salts with carboxylic acids or thioacids is reported for the facile access to chiral diarylmethanes. A Cu/[cyclopropyl bis(oxazoline)] catalyst well discriminates two C-I bonds of prochiral cyclic diaryliodonium salts. A stereochemical model was proposed to rationalize the stereochemical outcome on the basis of the crystal structure of cyclic diaryliodonium salt.
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