Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 140, Issue 27, Pages 8429-8433Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jacs.8b05343
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Funding
- CSIR-EMR-II grant [02(0259)/16/EMR-II]
- Ramanujan grant
- DST-Young Scientist grant
- CSIR
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An efficient strategy for the intramolecular denitrogenative transannulation/C(sp(2))-H amination of 1,2,3,4-tetrazoles bearing C8-substituted arenes, heteroarenes, and alkenes is described. The process involves the generation of the metal nitrene intermediate from tetrazole by the combination of [Cp*IrCl2](2) and AgSbF6. It has been shown that the reaction proceeds via an unprecedented electrocyclization process. The method has been successfully applied for the synthesis of a diverse array of alpha-carbolines and 7-azaindoles.
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