Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 140, Issue 15, Pages 5023-5027Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jacs.8b01800
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Funding
- NSERC of Canada [121]
- Government of Canada
- Killam Trusts
- Dalhousie University
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The use of (L)Ni(o-tolyl)Cl precatalysts (L = PAd-DalPhos or CyPAd-DalPhos) enables the C(sp(2))-cross-coupling of primary, secondary, or tertiary aliphatic alcohols with (hetero)aryl electrophiles, induding unprecedented examples of such nickel-catalyzed transformations employing (hetero)aryl chlorides, sulfonates, and pivalates. In addition to offering a competitive alternative to palladium catalysis, this work establishes the feasibility of utilizing ancillary ligation as a complementary means of promoting challenging nickel-catalyzed C(sp(2))-O cross-couplings, without recourse to precious metal photoredox catalytic methods.
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