Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 140, Issue 20, Pages 6186-6189Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jacs.8b00772
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Funding
- Ministry of Science and Technology of China [2016YFB04001100, 2013CB933403, 2013CB933504]
- National Natural Science Foundation of China [91222203, 91233205, 91433115, 51303185, 21473222]
- Chinese Academy of Sciences [XDB12030300]
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We report here a new ternary solvated (perylene-TCNB)center dot 2THF cocrystal, which can transform into binary perylene-TCNB cocrystal reversibly by successive desorption or absorption of THF solvent. As a consequence, macroscopic mechanical bending would be realized when repeated stimulation with THF solvent. The present results clearly demonstrated that solvent induced mechanical bending is driven by structural change at the molecular scale. Such solvatomechanical bending behavior is clearly revealed for the first time.
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