Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 140, Issue 8, Pages 2765-2768Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jacs.7b13433
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Funding
- CREST-JST [JPMJCR13L2:13418441]
- Program for Leading Graduate Schools Integrative Graduate Education and Research Program in Green Natural Sciences in Nagoya University
- JSPS
- Grants-in-Aid for Scientific Research [17H06446] Funding Source: KAKEN
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We describe the design, synthesis, and characterization of a chiral hexacoordinated phosphate ion that features an octahedral P(V) core consisting of two N,N,O-tridentate backbones. We further demonstrate that the corresponding hydrogen phosphate acts as an effective catalyst for a highly enantioselective Pictet-Spengler-type reaction, wherein the relationship between the structure of the chiral phosphate ion and its ability to dictate the absolute stereochemistry is revealed in conjunction with precise structural elucidation of the phosphate ion.
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