Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 140, Issue 6, Pages 2028-2031Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jacs.7b12913
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Funding
- Spanish MINECO [PN MAT2015-65354-C2-1-R, CTQ2015-64.561-R]
- Catalan AGAUR [2014 SGR 80]
- CERCA Program/Generalitat de Catalunya
- Generalitat de Catalunya
- Institut Universitaire de France (IUF)
- MINECO through the Severo Ochoa Centers of Excellence Program [SEV-2013-0295]
- [EU-FP7-ERC-Co-615954]
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We describe solid gas phase, single-crystal to-single-crystal, postsynthetic modifications of a metal organic framework (MOF). Using ozone, we quantitatively transformed the olefin groups of a UiO-66-type MOF into 1,2,4-trioxolane rings, which we then selectively converted into either aldehydes or carboxylic acids.
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