Journal
JOURNAL OF SUPERCRITICAL FLUIDS
Volume 134, Issue -, Pages 12-20Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.supflu.2017.12.022
Keywords
Mixed ionic liquids; Solvatochromism; Solubility; pVT; Equations of state
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Funding
- JSPS KAKENHI (Japan) [16H04549]
- Grants-in-Aid for Scientific Research [16H04549] Funding Source: KAKEN
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In this perspective, mixed ionic liquid acidity, basicity and dipolarity/polarizability are discussed in terms of Kamlet-Taft and Catalan polarity scales. Properties and experimentally-derived Henry's constants of mixed ionic liquids with CO2 are summarized. Then challenges and knowledge gaps are discussed in the areas of solvent polarity, solvent properties and solvent systems. The mixture of two ionic liquids with different functionalities combined with supercritical CO2 can provide a versatile biphasic solvent system for processing biomass and biomass-related compounds.
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