Journal
JOURNAL OF SOLID STATE CHEMISTRY
Volume 262, Issue -, Pages 244-250Publisher
ACADEMIC PRESS INC ELSEVIER SCIENCE
DOI: 10.1016/j.jssc.2018.03.029
Keywords
Ytterbium hexaboride (YbB6); Nanowire; Magnetoresistance; Electronic transport; Semiconductor-insulator transition (SIT)
Funding
- National Natural Science Foundation of China [51372089, 51672086]
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In this paper, we report the study of transport and magnetic properties of ytterbium hexaboride (YbB6) nanowires grown by a low trigger-temperature (200-240 degrees C) solid state method. The temperature dependence of resistivity shows that the YbB6 nanowire undergoes a semiconductor-insulator transition (SIT) below 20 K with an activation energy Delta E of 1 meV. The value of p at 2 K reaches 49 times the value of p at 300 K (p(2K)/p(300K) = 49). The observed non-saturating magnetoresistance (MR) has a linear relationship with B-2. The anomalous electronic transport in the YbB6 nanowire can be explained by the mixed valence of Yb ions due to the boron deficiency supporting by the X-ray photoelectron spectroscopy (XPS) and paramagnetic magnetization.
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