Journal
JOURNAL OF SEPARATION SCIENCE
Volume 41, Issue 6, Pages 1319-1337Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/jssc.201701264
Keywords
adsorption thermodynamics; chiral chromatography; Van't Hoff plot
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Funding
- Russian Foundation for Basic Research [16-53-45003]
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The present review discusses the theory and application of van't Hoff analysis in chiral chromatography, with main focus on liquid chromatography. The topics considered include the physical meaning of van't Hoff equation's parameters, interpretation of thermodynamic data in terms of retention and enantioseparation mechanisms, abnormal behavior of van't Hoff plots, and best practices to avoid biased results.
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