Journal
JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY
Volume 316, Issue 1, Pages 341-348Publisher
SPRINGER
DOI: 10.1007/s10967-018-5762-z
Keywords
Radiolysis; Organic chloride; Adsorption; Zeolite
Funding
- JSPS KAKENHI [15K06674]
- Grants-in-Aid for Scientific Research [15K06674] Funding Source: KAKEN
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This study aims to demonstrate that zeolite has the potential to increase the efficiency of radiolysis treatment of aqueous organic pollutants by concentrating the pollutants into the zeolite's pores. Using 2-chlorophenol (2-ClPh) as a model compound, we determined the high performance to be displayed by a mordenite-type zeolite (HMOR), which has a high silicon-to-aluminum ratio. HMOR adsorbed far more 2-ClPh than the other zeolites used in this study. We observed a significant increase in the radiolytic degradation efficiency of 2-ClPh in the presence of HMOR. Evidence shows that the high concentration of zeolite-adsorbed 2-ClPh facilitates radiation-induced degradation.
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