Journal
CHINESE JOURNAL OF CATALYSIS
Volume 35, Issue 2, Pages 242-246Publisher
SCIENCE PRESS
DOI: 10.1016/S1872-2067(12)60761-X
Keywords
Silica-bonded propylpiperazine-N-sulfamicacid; Aldehyde; Malononitrile; Amine; Solvent-free; 2-Hydroxynaphthalene-1,4-dione
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An efficient method for the synthesis of 2-amino-3-cyano-4-aryl-5,10-dioxo-5,10-dihydro-4H-benzo[g]chromenes and hydroxy-substituted naphthalene-1,4-dione derivatives, using silica-bonded propylpiperazine-N-sulfamic acid as a solid acid, green, heterogeneous catalyst, under ambient and solvent-free conditions, is described. A simple procedure, high yields, short reaction time, safety, and reusability of the catalyst are advantages of these protocols. (C) 2014, Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. All rights reserved.
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