Journal
JOURNAL OF POWER SOURCES
Volume 390, Issue -, Pages 186-196Publisher
ELSEVIER
DOI: 10.1016/j.jpowsour.2018.04.056
Keywords
Biomass waste; N-doped biomass-derived carbon; Supercapacitors; Lithium ion battery
Funding
- National Natural Science Foundation of China [21273185]
- National Found for Fostering Talents of Basic Science [J1310024]
Ask authors/readers for more resources
In this work, N-doped biomass derived porous carbon (NSBDC) has been prepared utilizing low-cost agricultural waste-sugarcane bagasse as the prototype, and needle-like PANI as the dopant. NSBDC possesses a special 3D interconnected framework structure, superior hierarchical pores and suitable heteroatom doping level, which benefits a large number of applications on ion storage and high-rate ion transfer. Typically, the NSBDC exhibits the high specific capacitance (298 F g(-1) at 1 A g(-1)) and rate capability (58.7% capacitance retention at 20 A g(-1)), as well as the high cycle stability (5.5% loss over 5000 cycles) in three-electrode systems. A two electrode asymmetric system has been fabricated employing NSBDC and the precursor of NSBDC (sugarcane bagasse derived carbon/PANI composite) as the negative and positive electrodes, respectively, and an energy density as high as 49.4 Wh kg(-1) is verified in this asymmetric system. A NSBDC-based whole symmetric supercapacitors has also been assembled, and it can easily light a 1.5 V bulb due to its high energy density (27.7 Wh kg(-1)). In addition, for expanding the application areas of NSBDC, it is also applied to lithium ion battery, and a high reversible capacity of 1148 mAh g(-1) at 0.1 A g(-1) is confirmed. Even at 5 A g(-1), NSBDC can still deliver a high reversible capacity of 357 mAh g(-1) after 200 cycles, indicating its superior lithium storage capability.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available