Pectin assisted one-pot synthesis of three dimensional porous NiO/graphene composite for enhanced bioelectrocatalysis in microbial fuel cells

A three dimensional (3D) porous nickel oxide (NiO)/graphene composite is developed through one-pot hydro thermal synthesis with a biopolymer-pectin for tailoring the porous structure. The introduction of pectin makes the NiO grow into nanoflakes-assembled micro spheres that insert in the graphene layers rather than just deposit on the surface of graphene nanosheets as nanoparticles. As the increase of pectin ratio, the size and the amount of NiO micro spheres are both increased, which resulting a 3D hierarchical porous structure. With the optimized pectin concentration, the obtained NiO/graphene nanocomposite anode possesses good electrocatalytic capability and delivers maximum power density of 3.632 Wm(-2) in Shewanella putrefaciens CN32 microbial fuel cells (MFCs). This work provides a new way to develop low cost, high performance anode materials for MFCs.