4.5 Article

Mobility gap and quantum transport in a functionalized graphene bilayer

Journal

JOURNAL OF PHYSICS-CONDENSED MATTER
Volume 30, Issue 19, Pages -

Publisher

IOP PUBLISHING LTD
DOI: 10.1088/1361-648X/aaba06

Keywords

graphene bilayer; quantum transport; electronic structure; functionalization

Funding

  1. Tunisian French Cooperation Project [CMCU 15G1306]
  2. [ANR-15-CE24-0017]

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In a Bernal graphene bilayer, carbon atoms belong to two inequivalent sublattices A and B, with atoms that are coupled to the other layer by p(sigma) bonds belonging to sublattice A and the other atoms belonging to sublattice B. We analyze the density of states and the conductivity of Bernal graphene bilayers when atoms of sublattice A or B only are randomly functionalized. We find that for a selective functionalization on sublattice B only, a mobility gap of the order of 0.5 eV is formed close to the Dirac energy at concentration of adatoms c >= 10(-2). In addition, at some other energies conductivity presents anomalous behaviors. We show that these properties are related to the bipartite structure of the graphene layer.

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