4.8 Article

Insight into Water-Soluble Highly Fluorescent Low-Dimensional Host-Guest Supramolecular Polymers: Structure and Energy-Transfer Dynamics Revealed by Polarized Fluorescence Spectroscopy

Journal

JOURNAL OF PHYSICAL CHEMISTRY LETTERS
Volume 9, Issue 14, Pages 3870-3877

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/acs.jpclett.8b01562

Keywords

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Funding

  1. Severo Ochoa program of the Spanish Ministerio de Economia y Competitividad for Centers of Excellence in RD (MINECO) [SEV-2016-0686]
  2. MINECO-FEDER [CTQ2014-58801, CTQ2017-87054]
  3. Comunidad de Madrid (Project Mad2D) [S2013/MIT-3007]
  4. Campus of International Excellence (CEI) UAM+CSIC
  5. EC via the COFUND program AMAROUT
  6. Severo Ochoa program
  7. Creative Research Initiative Program through the National Research Foundation of Korea (NRF) - Ministry of Science, ICT & Future Planning (MSIP) [2009-0081571[RIAM0417-20150013]]
  8. Basic Science Research Program through the NRF - Ministry of Science, ICT and Future Planning [2017R1E1A1A01075372]

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Water-soluble, highly fluorescent host guest chromophore-cucurbit[8]uril supramolecular polymer bundles are investigated by polarized time-resolved photoluminescence spectroscopy, structural methods, and quantum chemistry to fully reveal structural organization and heterogeneity but, in particular, energy-transfer dynamics, being of crucial importance for the design of supramolecular artificial light-harvesting systems.

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