Journal
JOURNAL OF PHYSICAL CHEMISTRY LETTERS
Volume 9, Issue 11, Pages 3087-3092Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.jpclett.8b01116
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Funding
- National Natural Science Foundation of China [21533010]
- National Key Research and Development Program of China [2017YFA0204800]
- DICP [DMTO201601, ZZBS201703]
- Science Challenging Program [JCKY2016212A501]
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We developed a high-performance photodetector based on (CH3NH3)(3)Sb2I9 (MA(3)Sb(2)I(9)) microsingle crystals (MSCs). The MA(3)Sb(2)I(9) single crystals exhibit a low-trap state density of similar to 10(10) cm(-3) and a long carrier diffusion length reaching 3.0 mu m, suggesting its great potential for optoelectronic applications. However, the centimeter single crystal (CSC)-based photodetector exhibits low responsivity (10(-6) A/W under 1 sun illumination) due to low charge-carrier collection efficiency. By constructing the MSC photodetector with efficient charge-carrier collection, the responsivity can be improved by three orders of magnitude (under 1 sun illumination) and reach 40 A/W with monochromatic light (460 nm). Furthermore, the MSC photodetectors exhibit fast response speed of <1 ms, resulting in a high gain of 10(8) and a gain-bandwidth product of 10(5) Hz. These numbers are comparable to the lead-perovskite single-crystal-based photodetectors.
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