Journal
JOURNAL OF PHYSICAL CHEMISTRY C
Volume 122, Issue 25, Pages 13944-13952Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.jpcc.8b01123
Keywords
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Funding
- Air Force Office of Scientific Research [FA9550-17-0198]
- Office of Biological and Environmental Research
- National Science Foundation Graduate Research Fellowship [DGE-1122492]
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Monolayers of fac-Re(4,4'-dicarboxy1-2,2'-bipyridine)(CO)(3)Cl (ReCOA) complexes, covalently bound to TiO2-terminated SrTiO3 (100) (STO) single crystals, were studied by both vibrational Sum Frequency Generation (SFG) spectroscopy and Density Functional Theory (DFT). Homodyne-detected SFG results show that the SFG spectral shape of ReCOA on Nb-doped STO surfaces is almost opposite to that of ReCOA on undoped or Fe-doped STO surfaces, which we assign to a phase change of the SFG response of STO induced by the Nb rather than a change in orientation of the molecule. DFT calculations show that the doping with Nb populates the conduction band of the system, giving a metallic nature to the otherwise insulator STO substrate. This change in electronic structures of the substrate leads to a big nonresonant SFG response and thus interference with the spectra. The orientation of the ReCOA on all three substrates was found to be tilted by similar to 45-50 degrees with a bidentate binding geometry and the CI atom facing the surface. The reported results indicate that a molecular probe can be used to obtain information about the underlying material.
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