The Influence of the Work Function of Hybrid Carbon Electrodes on Printable Mesoscopic Perovskite Solar Cells

In printable mesoscopic perovskite solar cells (PSCs), carbon electrodes play a significant role in charge extraction and transport, influencing the overall device performance. The work function and electrical conductivity of the carbon electrodes mainly affect the open-circuit voltage (Voc) and series resistance (R,) of the device. In this paper, we propose a hybrid carbon electrode based on a high-temperature mesoporous carbon (m-C) layer and a low-temperature highly conductive carbon (c-C) layer. The m-C layer has a high work function and large surface area and is mainly responsible for charge extraction. The c-C layer has a high conductivity and is responsible for charge transport. The work function of the m-C layer was tuned by adding different amounts of NiO, and at the same time, the conductivities of the hybrid carbon electrodes were maintained by the c-C layer. It was supposed that the increase of the work function of the carbon electrode can enhance the Voc of printable mesoscopic PSCs. Here, we found the Voc of the device based on hybrid carbon electrodes can be enhanced remarkably when the insulating layer has a relatively small thickness (500-1000 nm). An optimal improvement in Voc of up to 90 mV could be achieved when the work function of the m-C was increased from 4.94 to 5.04 eV. When the thickness of the insulating layer was increased to similar to 3000 nm, the variation of Voc as the work function of m-C increased became less distinct.