Anisotropic Proton Conductivity Arising from Hydrogen-Bond Patterns in Anhydrous Organic Single Crystals, Imidazolium Carboxylates

Organic acid base salts have attracted increasing attention as a promising candidate of anhydrous proton conductors. In this study, we have successfully disclosed the relationship between proton conductivity and hydrogen-bond (H-bond) interactions in such kinds of organic salts, composed of dicarboxylic acid and imidazole. We have grown high-quality single crystals of imidazolium succinate (Im-Suc) or glutarate (Im-Glu) with two-dimensional H-bonding networks and measured the proton conductivity within and perpendicular to the networks. On the basis of the observed intrinsic proton conductivities without grain boundary contributions, their relationship to the crystal structure and molecular arrangement was investigated in detail. Importantly, in both materials, the proton conductivities within the H-bonding networks are almost 2 orders of magnitude higher than those perpendicular to the networks, demonstrating that the proton conduction is highly mediated by the H-bonds. In addition, a suitable combination and arrangement of acid and base molecules for realizing high proton conductivity is discussed in terms of their proton donating/accepting abilities (pK(a)) and molecular motions. These results provide important insights into the effects of H-bonds on proton conductivity in this kind of anhydrous organic acid base salts.