Journal
JOURNAL OF PHYSICAL CHEMISTRY A
Volume 122, Issue 7, Pages 1838-1854Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.jpca.7b11623
Keywords
-
Ask authors/readers for more resources
The present experimental and theoretical study on a new chromophore DMAMN of the type push-pi-pull (push = dimethylaniline, pi = imine, pull = 2-naphthoic acid), allows understanding of the mechanism by which the molecular conformational undergoes isomerization/rotomerization following electronic excitation. The steady-state fluorescence spectra of this compound, carried out in solvents of different polarities and proticities, showed significant changes in both the shape and peak positions. The wavelength and intensity change depend on the polarity and hydrogen-bonding environment. In highly polar solvents, the emission is weak and red-shifted compared to that for cyclohexane, but it is more red-shifted in moderate aprotic polar solvents. In hydroxyl solvents, a new weak low-energy emission band appears at similar to 525 nm, attributed to the intermolecularly H-bonded open conformer. On the basis of the generated potential energy landscapes of the ground state and low-lying excited state in gas phase and solution, we found that selective photon absorption, brings this molecule to a bright state, from which N=C isomerization Z -> E, takes place. This isomerization in gas-phase and low-polarity solvents leads to two minima with a barrier, whereas in highly polar-protic media, it gives one minimum on the Si surface with low Delta E-s1/T1 (0.17 eV), facilitating deactivation via ISC.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available