Journal
JOURNAL OF ORGANOMETALLIC CHEMISTRY
Volume 861, Issue -, Pages 17-104Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jorganchem.2018.02.023
Keywords
Pd-catalyzed; Buchwald-Hartwig amination reaction; Total synthesis; Natural products
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Funding
- Iran National Science Foundation (INSF)
- Alzahra University Research Council
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Pd-catalyzed amination reaction of aryl halides has attracted much attention in recent years. This review underscores selected important recent developments in the catalysis of one of the kind amination reaction so-called Buchwald-Hartwig amination reaction. This development has been achieved via utilization of sterically hindered phosphine ancillary ligands. Our purpose here is giving information to the readers about recent advances in this strategy for the C-N bond formation, especially applied for construction of various heterocyclic systems. In this review, we also deliberate the applications of this name reaction as an important C-N cross-coupling reaction applied to the total synthesis of natural products. (C) 2018 Elsevier B.V. All rights reserved.
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