Journal
JOURNAL OF ORGANOMETALLIC CHEMISTRY
Volume 864, Issue -, Pages 19-25Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jorganchem.2017.12.026
Keywords
C-H activation; Pd catalysis; Ag salts; Bimetallic catalysis; Pd-Ag cooperativity; Heterometallic synergism
Categories
Funding
- National Science Foundation under the CCI Center for Selective C-H Functionalization [CHE-1700982]
Ask authors/readers for more resources
Many Pd-catalyzed C-H functionalization reactions utilize stoichiometric Ag(I)-salts as additives. Ag additives are typically used either as a terminal oxidant or as a halide scavenger for Pd catalyst regeneration. However, recent experimental and computational studies have shown that Ag(I)-salts may play additional roles in C-H activation processes. Notably, cooperative Pd-Ag bimetallic C-H activations and Ag(I)-mediated Pd-catalyzed C-H arylations can occur. The non-oxidative roles of Ag(I) salts in Pd-catalyzed C-H activation are highlighted in this mini-review. (C) 2017 Elsevier B.V. All rights reserved.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available