Journal
JOURNAL OF ORGANOMETALLIC CHEMISTRY
Volume 866, Issue -, Pages 123-143Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jorganchem.2018.04.021
Keywords
Half-sandwich compounds; Transfer hydrogenation; Oxidation; Biological applications; Ru; Os; Rh; Ru
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Funding
- NRF, THRIP [TP 1208035643]
- UKZN (URF)
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Half-sandwich complexes of the platinum group metals serve as excellent precursors and find many applications in biological and catalytic applications. This review focuses on the synthesis, biological and catalytic applications of half-sandwich complexes of iridium, rhodium, ruthenium and osmium reported over the last three years. For the catalytic applications the focus will be on catalytic oxidation and transfer hydrogenation. In addition, for biological applications the focus will be on anticancer and antibacterial applications. (C) 2018 Elsevier B.V. All rights reserved.
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