Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 83, Issue 18, Pages 11125-11132Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.8b01731
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Funding
- MINECO [CTQ2017-82893-C2-1-R]
- MINECO (Juan de la Cierva fellowship)
- Junta de Andalucia [P12-FQM-1765]
- CHAOS COST ACTION [CA-15106]
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The selective catalytic functionalization of the C-H bond of azulene upon incorporation of carbene or nitrene units with metal-based catalysts is described. Ethyl diazoacetate or ArI=NTs are employed as carbene or nitrene precursors, respectively. The azulene derivatives are subsequently employed as building blocks toward more complex structures with potential use as biodegradable materials.
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