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Bronsted Acid-Promoted Friedel-Crafts Alkylation/Cyclization of (7-Hydroxynaphthalenyl)pyrrole or (2-Hydroxyphenyl)pyrroles with Isatins for the Construction of Pyrrolospirooxindole Derivatives

JOURNAL OF ORGANIC CHEMISTRY (2018)

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Journal

JOURNAL OF ORGANIC CHEMISTRY
Volume 83, Issue 18, Pages 11407-11414

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.8b01703

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Categories

Chemistry, Organic

Funding

  1. Chinese Academy of Sciences (CAS)
  2. National Natural Science Foundation of China [21602231]
  3. Natural Science Foundation of Jiangsu Province [BK20151235, BK20160396]

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An efficient trifluoroacetic acid-catalyzed cascade Friedel-Crafts alkylation/cyclization of 1-(7-hydroxynaphthalenyl)pyrrole or 1-(2-hydroxyphenyl)pyrroles with isatins has been developed, providing practical access to a variety of biologically important pyrrole-containing spirooxindoles.

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