Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 83, Issue 15, Pages 8710-8715Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.8b00965
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Funding
- National Natural Science Foundation of China [21462023, 21762021]
- Natural Science Foundation of Jiangxi Province [20161BAB213069]
- Science and Technology Project of Jiangxi Provincial Education Department [GJJ150297, GJJ150324]
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An efficient palladium-catalyzed Suzuki coupling of 1,1-diarylmethyl-trimethylammonium triflates with arylboronic acids is reported. This reaction offers a novel approach to triarylmethane derivatives in good to excellent yields with the palladium-catalyzed C-N bond cleavage as the key feature. Broad substrate scope regarding both reaction partners are observed. Moreover, reactive functional groups such as vinyl and formyl groups are conserved in this transformation.
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