Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 83, Issue 18, Pages 11377-11384Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.8b01624
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Funding
- European Union [641861]
- Dutch Science Foundation (NWO) [14150]
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A convenient method for the preparation of sp(3)-rich heterocycles is reported. The method comprises a photocatalytic difluoroalkylation-induced 1,2-heteroarene migration of allylic alcohols. Here we describe for the first time the benefits of using flow to facilitate such migration reactions, including shorter reaction times, higher selectivities, and opportunities to scale the chemistry.
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