Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 83, Issue 16, Pages 9442-9448Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.8b01094
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Funding
- American Chemical Society Petroleum Research Fund [54247-UNI3]
- CUNY Collaborative Research Incentive Program
- PSC-CUNY awards [69069-0047, 60328-0048]
- Office for Advancement of Research at John Jay College
- National Science Foundation [CHE-1429086]
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Highly effective hydroboration precatalyst is developed based on a cobalt(II)-terpyridine coordination polymer (CP). The hydroboration of ketones, aldehydes, and imines with pinacolborane (HBpin) has been achieved using the recyclable CP catalyst in the presence of an air-stable activator. A wide range of substrates containing polar G=O or C=N bonds have been hydroborated selectively in excellent yields under ambient conditions.
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