Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 83, Issue 8, Pages 4674-4680Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.8b00447
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Funding
- National Natural Science Foundation of China [21472082, 21772085, 21761132021]
- Collaborative Innovation Center of Solid-State Lighting and Energy-Saving Electronics
- Changzhou Jin-Feng-Huang program
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A Cu-catalyzed multicomponent cascade reaction of DABCO center dot(SO2)(2) (DABSO), alcohol, and aryl diazonium tetrafluoroborate was developed which afforded sulfonic esters in moderate to good chemical yields. In this reaction, the SO2 surrogate DABSO was used for the first time in the synthesis of sulfonic aliphatic esters. This multi component reaction was carried out under mild conditions and tolerated a wide range of substrates, which provides a new and efficient strategy for the synthesis of sulfonic esters.
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