Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 83, Issue 6, Pages 3245-3251Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.8b00149
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Funding
- Chinese NSF [81773565, 81430080]
- National Program on Key Basic Research Project of China [2015CB910603]
- International Cooperative Program [GJHZ1622]
- Key Program of the Frontier Science of the Chinese Academy of Sciences [QYZDJ-SSW-SMC002]
- Shanghai Commission of Science and Technology [16XD1404600]
- Chinese NSF [81773565, 81430080]
- National Program on Key Basic Research Project of China [2015CB910603]
- International Cooperative Program [GJHZ1622]
- Key Program of the Frontier Science of the Chinese Academy of Sciences [QYZDJ-SSW-SMC002]
- Shanghai Commission of Science and Technology [16XD1404600]
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[Graphics] To address the challenge of meta nitration of 6-arylpurine substrates, a versatile ruthenium catalyzed meta C-H nitration is developed. The use of a sterically hindered phosphine ligand is crucial for the catalytic efficiency, and a broad class of 6-arylpurines and nucleosides were found suitable for this process providing corresponding exclusively meta nitrated products in good yields.
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