Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 83, Issue 16, Pages 9156-9165Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.8b01207
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Funding
- National Natural Science Foundation of China [21472056, 21772051]
- Doctoral Scientific Research Startup Foundation of Yangtze University [801090010135]
- Yangtze Youth Talents Fund [2016cqn25]
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An interesting sigma-bond insertion/benzannulation reaction for the synthesis of polysubstituted naphthalene derivatives has been developed from readily accessible ketones, arynes, and alkynoates. This practical and transition -metal-free method provides a novel route to diverse naphthalenes through a substrate-controlled rearrangement reaction with the cleavage of C-C bonds.
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