Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 83, Issue 2, Pages 578-587Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.7b02354
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Funding
- National Science Foundation of China [21572099, 21332005]
- Natural Science Foundation of Jiangsu Province [BK20151379]
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Visible-light-induced catalytic hydrophosphonodifluoromethylation of mono- and disubstituted alkenes using bromodifluoromethanephosphonate with a Hantzsch ester as the terminal reductant is reported. The combination of thiyl-radical catalysis with photoredox catalysis is important for achieving good chemoselectivity and high yields.
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