Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 83, Issue 2, Pages 1065-1072Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.7b02885
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Funding
- National Natural Science Foundation of China [21372176, 21672162]
- Shanghai Science and Technology Commission [14DZ2261100]
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9,9-Disubstituted fluorenes are widely employed in materials science. We have developed a straightforward approach for the synthesis of 9,9-disubstituted fluorenes from 2-iodobiphenyls and alpha-diazoesters. The reaction proceeds via a tandem palladium-catalyzed C(sp(2))-H activation/carbenoid insertion sequence.
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