Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 83, Issue 5, Pages 2993-2999Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.8b00016
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Funding
- National Natural Science Foundation of China [31670357]
- Hangzhou Science and Technology Information Institute of China [20150633B45]
- National Science Foundation [CHE-1464744]
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A novel nickel-catalyzed C(sp(3))-H arylation with nonactivated aryl fluorides is reported. The use of 1,3-bis(2,4,6-trimethylphenyl)imidazol-2-ylidene (IMes) as a ligand was found to be critical to the success of the reaction. This new method enables the synthesis of a wide range of triarylmethane derivatives.
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