4.7 Article

[2]Catenanes Displaying Switchable Gin-Trap-Like Motion

Journal

JOURNAL OF ORGANIC CHEMISTRY
Volume 83, Issue 10, Pages 5619-5628

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.8b00601

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Funding

  1. Ministry of Science and Technology (Taiwan) [MOST-106-2628-M-002-002, MOST-106-2113-M-002-011]
  2. National Taiwan University [NTU-106R880202]

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Sodium ion-controlled switching from folded to linear states results in significant changes in the molecular shape of a [2]catenane, such that it mimics the operation of a gin trap, with a fluorescent alarm signal appearing when pyrene side arms were present on its two macrocyclic components.

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