Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 83, Issue 9, Pages 5072-5081Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.8b00402
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Funding
- American Chemical Society Petroleum Research Fund Doctoral New Investigator Program (PRF) [54824-DNI1]
- Duke University
- Kathleen Zielik fellowship
- NSF [CHE-0923097]
- NIH, HHMI
- North Carolina Biotechnology Center
- Duke (Duke Magnetic Resonance Spectroscopy Center)
- NSF
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Herein described are the first efficient nitrogen atom transfer reactions mediated by iron N,N'-dimethyl-N,N'-bis(2-pyridinylmethyl)cyclohexane-1,2-diamine-(MCP-) and 2-({1-[(pyridin-2-ylmethyl)pyrrolidin-2-yl]pyrrolidin-1-yl}- methyppyridine-type (PDP-type) complexes. These catalysts affect styrene aziridination under mild conditions based on a limiting quantity of olefin substrate.
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