Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 83, Issue 4, Pages 2250-2255Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.7b03139
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Funding
- China Postdoctoral Science Foundation [2017M621972]
- Chemical Engineering and Technology of Zhejiang Province First-Class Discipline (Taizhou University)
- National Natural Science Foundation of China [21375092]
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We report an additive-free, base-catalyzed C-, N-, O-, and S-Si bond cleavage of various organosilanes in mild conditions. The novel catalyst system exhibits high efficiency and good functional group compatibility, providing the corresponding products in good to excellent yields with low catalyst loadings. Overall, this transition-metal-free process may offer a convenient and general alternative to current employing excess bases, strong acids, or metal-catalyzed systems for the protodesilylation of organosilanes.
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