Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 83, Issue 7, Pages 4099-4104Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.7b03274
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Funding
- Swedish Research Council (Formas)
- Stiftelsen Olle Engkvist Byggmastare
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Nonactivated phenols have been employed as nucleophiles in the allylation of nonderivatized allylic alcohols to generate allylated phenolic ethers with water as the only byproduct. A Pd[BiPhePhos] catalyst was found to be reactive to give the O-allylated phenols in good to excellent yields in the presence of molecular sieves. The reactions are chemo-selective in which the kinetically favored O-allylated products are formed exclusively over the thermodynamically favored C-allylated products.
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