Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 83, Issue 7, Pages 4197-4203Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.8b00197
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Funding
- National Research Foundation of Korea (NRF) - Korean government [2014R1A5A1011165, 2007-0093864]
- BK21 plus Fellowship
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The [Rh(COD)Cl](2)/xantphos/Cs2CO3 system efficiently catalyzes the reductive N-alkylation of aryl nitro compounds with alcohols by a borrowing-hydrogen strategy to afford the corresponding imine products in good to excellent yields. In the absence of xantphos, the [Rh(COD)Cl](2)/Cs2CO3 catalytic system behaves as an effective catalyst for the dehydrogenative coupling of alcohols to esters, with nitrobenzene as a hydrogen acceptor. The reactivity of the rhodium catalytic system can be easily manipulated to selectively afford the imine or ester.
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