Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 83, Issue 7, Pages 4250-4256Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.8b00279
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Funding
- National Natural Science Foundation of China [21202009, 21672217]
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Asymmetric fluorination of alpha-branched aldehydes catalyzed by chiral primary amines under mild conditions has been developed. Both enantiomers could be obtained with good yields (up to 96%) and a high enantioselectivity (up to 90% ee) by a simple swap of the fluorination reagents.
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