Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 83, Issue 5, Pages 2592-2600Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.7b02986
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Funding
- Natural Science Foundation of China [21372033]
- Zhejiang Provincial National Science Foundation of China [LY18B020002, LQ15B020001]
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A highly regio-and stereoselctive palladium-catalyzed domino reaction of functionalized aryl allyl ethers has been developed. Various aryl allyl ethers derived from the phosphine-catalyzed addition of electron-deficient allenes with phenol are found to be efficient substrates for the synthesis of 2-substituted 2,3-dihydrobenzofurans and indolines. It is the first example of aryl allyl ether used as an ideal and practical precursor of hard to get functionalized 1,3-butadiene for the heterocyclic compound synthesis.
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