Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 83, Issue 2, Pages 754-764Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.7b02747
Keywords
-
Categories
Funding
- NSFC [21732005, 21702140]
- China Postdoctoral Science Foundation [2017M610608]
Ask authors/readers for more resources
[GRAPHICS] The formal total syntheses of ()-actinophyllic acid and its enantiomer starting from the same chiral intermediate are reported. The synthesis features a photoredox organocatalytic asymmetric alkylation to generate the original C15 chirality, a photocatalytic C-H functionalization of 3-methylindole in flow for constructing the C16 all-carbon quaternary center, a regioselective 1,3-dipolar cycloaddition, and an intramolecular Henry reaction to assemble the pentacydic core of the target molecule.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available