Journal
GREEN CHEMISTRY
Volume 17, Issue 4, Pages 2330-2334Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5gc00079c
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Funding
- National Natural Science Foundation of China [21376221, 21176222, 21276238]
- Natural Science Foundation of Zhejiang Province [LY13B020015]
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Chiral propargylamines were synthesized in good to excellent yields with high enantioselectivity via Cu(OTf)(2)/Ph-Pybox catalysed, solvent-free three-component asymmetric coupling of aldehydes, alkynes and amines by ball-milling within 60 minutes. The catalytic system can be reused several times without losing the activity.
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