Journal
GREEN CHEMISTRY
Volume 17, Issue 1, Pages 300-306Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4gc01353k
Keywords
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Funding
- DAAD
- EPSRC [EP/L017393/1, EP/K014070/1]
- EPSRC [EP/K014676/1, EP/K035274/1, EP/H046380/1, EP/K039946/1] Funding Source: UKRI
- Engineering and Physical Sciences Research Council [EP/K014676/1, EP/H046380/1, EP/L017393/1, EP/K039946/1, EP/K035274/1, EP/C544846/1, EP/C544838/1] Funding Source: researchfish
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Epoxides derived from 1,4-cyclohexadiene (CHD), the latter produced from renewable resources via self-metathesis of plant oil derivatives, are applied as key substrates in ring-opening copolymerizations to produce aliphatic polycarbonates and polyesters. Renewable, unsaturated polycarbonates are prepared by the ring-opening copolymerization of epoxide/CO2; these are catalysed by di-zinc/magnesium complexes previously reported by Williams et al. or by using chromium(III) or cobalt(III) salen complexes. Renewable, unsaturated polyesters, with glass transition temperatures up to 128 degrees C, were obtained by the ring-opening copolymerization of epoxide/phthalic anhydride. The relative rates of these copolymerizations were monitored using in situ attenuated total reflectance infra-red (ATR-IR) spectroscopy. The polymers were fully characterized using spectroscopy (nuclear magnetic resonance, infra-red), mass spectrometry (matrix assisted laser desorption ionization), and by thermal methods (differential scanning calorimetry and thermogravimetric analysis).
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